The decomposition products of sulfur hexafluoride (sf 6

Nov 01, 2007 · Trifluoromethyl sulfur pentafluoride (SF 5 CF 3), first detected in 1999, is also a SF 6 decomposition product with its atmospheric lifetime and GWP-100-year time horizon on the order of 1000 years and 20,000, respectively, suggesting that it is a highly radioactive-forcing greenhouse gas.Get price

Decomposition of sf6 gas in an RF Plasma Environment

Tainan, Taiwan Chuh-Yung Chen Department of Chemical Engineering, National Cheng Kung University, Tainan, Taiwan IMPLICATIONS RF plasma was used to decompose SF 6. The results showed that, at a power of 40 W, the decomposition frac-tion of SF 6 exceeded 99% under various conditions, and reaction products were mostly stable compounds, such as SiF 4, SO 2, and F 2Get price

Sulfr hexafluoride Gas analyzer - GA11 - WIKA Taiwan

The model GA11 Sulfr hexafluoride Gas analyzer are innovative and reliable instruments for determining the quality of different insulating gases. Among these insulating gases are included SF 6 , Novec™ 4710 gas mixture (g 3 gas) as well as applications for technical air (clean air/ dry air, based on oxygen and nitrogen).Get price

insulating gas Decomposition in Gas-Insulated Equipment - IEEE Journals

sf6 gas Decomposition in Gas-Insulated Equipment Abstract: The increasing application of gaz sf6 as an insulating gas has led to many studies on Sulfr hexafluoride decomposition in gas-insulated equipment. In the presence-of an electric arc, spark or corona, sf 6 decomposes to a wide variety of chemically active products which possess completely different properties from Sulfr hexafluoride.Get price

The Decomposition Products of Sulfur Hexafluoride (sf 6) with

The Decomposition Products of Sulfur Hexafluoride (sf6 gas) with Metals Dissolved in Liquid Ammonia Holger Lars Deubner and Florian Kraus * Fachbereich Chemie, Philipps-Universität Marburg, 35043 Marburg, Germany; [email protected] * Correspondence: fl[email protected]; Tel.: +49-6421-28-26668Get price

Mechanism of Formation of SF Decomposition Gas Products and

reaction of decomposition products with water and oxygen are shown in Fig. 2. It can be seen that the major products of the decomposition reaction are sulphur oxides, while others are fluoride compounds. The concentrations of decomposition products are directly dependent on spark conditions and energy. Figure 2. The formation of SF 6Get price

(PDF) The gaz sf6 Decomposition Mechanism: Background and

The result shows that: sf 6 begins to decompose obviously at 300°C and the main decomposition components contain CO2, SO2F2, SOF2, SOF4, SO2 and H2S; the improvement of fault temperature willGet price

(PDF) Mechanism of Formation of sf 6 Decomposition Gas

The sf 6 is commonly used as an insulating gas in different applications; however the gaz sf6 can be easily exploded into different decomposition gas products when subjected to electrical discharge,...Get price

Measuring system for laboratory analysis of decomposition

Non-destructive method of measurement The advantage of the GFTIR-10 is the non-destructive determination of the most-important decomposition products, which are also able to quantify high concentrations of reactive and highly-corrosive substances.Get price


Jan 01, 2013 · Mixtures of Sulfr hexafluoride and air after passage through a lighted cigarette tip were analyzed for SF5 decomposition products. The insulating gas concentration in the mixture ranged from 0.1% to 6.5%. The gaseous mixture in a 60 L mixing tank was drawn through the tip of the cigarette by a pump into a Tediar gas sampling bag.Get price

The impact of decomposition products in SF 6 on the

decomposition products resulting from partial discharges [6]. The following study presents a report on the results of tests in which SF 6-decomposition products are produced through partial discharges, and interactions with electrically stressed epoxy resin surfaces are enabled. 1. Experimental set-up and realisationGet price

Decomposition Characteristics of Sulfr hexafluoride and Partial Discharge

experiments of Sulfr hexafluoride gas to obtain and understand the decomposition characteristics of gaz sf6 gas-insulated medium under different types of negative DC partial discharge (DC-PD), and use the obtained decomposition characteristics of gaz sf6 in diagnosing the type and severity of insulation fault in DC sf 6 gas-insulated equipment. Experimental results show that the negative DC partialGet price

China High Precision Sf6 Gas Discharge Decomposition Product

Sulfr hexafluoride Gas Decomposition Tester uses the worldmost advanced UK Alpha high-performance, high resolution electrochemical sensors, embedded computer technology, is high-precision intelligent instrumentation. By detecting gaz sf6 insulating material inside the device main cleavage product -SO2, the content of H2S, HF and CO , can quickly and accurately determine the early failure Sulfr hexafluoride circuit breakers, transformers , GIS, busbars, bushings and transformers and other electrical equipment inside forGet price

Decomposing Mechanism of Sulfr hexafluoride under Positive DC Partial

The experimental platform for decomposing SF 6 under DC PD is shown in Figure 9, with a chamber volume of 15 L, needle electrode diameter of 4 mm, needle tip curvature radius of 0.3 mm, closed cone angle of 30°, ground electrode diameter of 120 mm, ground electrode thickness of 10 mm, and a needle–plate gap of 8 mm.Get price

Implementation Of Treatment Recovery Of the Sulfr hexafluoride Gas

the normal current interruptions in switchgear are leading to the formation of decomposition products of SF 6. Such decomposition products are numerous and various (HF / SO 2 / SiF 4 / SOF 4 / SF 4/ S 2F 10 / CO 2/ CF 4 / SO F 2/ SO 2F 2 / H 20) as well as oxides and various powders either free or combined with metals (figure 6).Get price

Experimental study on the relationship between partial

Sulfr hexafluoride decomposition serves as an effective means for online fault detection and diagnosis of Sulfr hexafluoride insulated equipments. The relationship between sf6 gas decomposition products and partial discharge (PD) in gaz sf6 insulated equipments remains a significant theoretical and practical issue to be addressed. Based on the simulations of protrusion discharge, floating discharge and surface discharge in sf 6Get price

China Zc-317D Sf6 Gas Discharge Decomposition Analyzer

sf 6 Gas Decomposition Tester uses the worldmost advanced UK Alpha high-performance, high resolution electrochemical sensors, embedded computer technology, is high-precision intelligent instrumentation. By detecting insulating gas insulating material inside the device main cleavage product -SO2, the content of H2S, HF and CO , can quickly and accurately determine the early failure Sulfr hexafluoride circuit breakers, transformers , GIS, busbars, bushings and transformers and other electrical equipment inside forGet price

The gaz sf6 Decomposition Mechanism: Background and Significance

Jan 24, 2017 · Extensive domestic and overseas studies show that when PD occurs in SF 6 gas-insulated equipment, SF 6 will decompose under the effect of electric field energy and generate low fluorine sulfide products such as SF 5, SF 4, SF 3, SF 2, SF, etc. [ 17 ].Get price

Sulfr hexafluoride decomposition components under different metallic free

The change rules of five main characteristic decomposition components, namely, CF 4, CO 2, SOF 2, SO 2 F 2, and SO 2, under different free‐conducting metal particles were obtained using gas chromatography–mass spectrometry quantitative detection.Get price

Theoretical study of the decomposition mechanism of Sulfr hexafluoride/Cu

Sep 10, 2018 · The compositions of SF 6 arc plasma are contaminated by Cu vapor through electrode erosion and thus affect the performance of the high-voltage SF 6 circuit breaker. But the essential data for chemical kinetic models to study the non-equilibrium compositions of SF 6 /Cu mixtures, namely the decomposition mechanism of SF 6 /Cu mixtures, is still not clear.Get price

Spectrum Analyzers, Taiwan Spectrum Analyzers Manufacturers

The LK405 Sulfr hexafluoride Decomposition SO2 ,HF,H2S Content/ Purity /Moisture Analyzer adopt the advanced technology of Photo-Acoustic Spectroscopy(PAS) Link Electric ( Shenzhen ) Co., Ltd . Add to Inquiry CartGet price

Decomposition Characteristics of sf 6 under Flashover

In this paper, the flashover discharging experiment was carried out on epoxy resin surface in an gaz sf6 atmosphere under pin-plate electrodes, with the electrodes distance from 5 mm to 9 mm. The concentration of seven characteristic gases was detected, indicating that the concentration of SOF2 and CF4 was the two highest, followed by SO2, CO2, SO2F2, CS2, and H2S. Based on the changes in theGet price

Occupational Hygiene Aspects of SF Decomposition By-Products

Decomposition By-Products Issue Brief •Provides background •Describes processes and resulting by-products, based on past work –Arc –Spark discharge –Corona/partial discharge •Discusses field detection instrumentation and use of PPE December 2011 Product ID: 1023109Get price

Comparative Study of Materials to Sulfr hexafluoride Decomposition

Feb 07, 2017 · To detect, evaluate, and diagnose the insulation status of SF 6 gas insulated equipment using the characteristics of SF 6 decomposition, a series of characteristic SF 6 decomposition components, SOF 2, SO 2 F 2, SO 2, H 2 S, CF 4, HF, and SF 6, are detected by gas sensors, including metal functionalized single wall carbon nanotubes (SWCNTs) [1–6], TiO 2 nanotubes [7–9], and graphene gas sensors [10, 11], as shown in Table 1.Get price


(Sulfr hexafluoride ). uj=u-Uo) h(2Jo+ l)Pvib (EVib) (3) x f ~;:duct(x)LJ LL (2J+l)dx,.x=o assuming that (sf 6-)* and po lyatomic products of its decomposition can be treated as spherical tops. In the expression above Pvib is the vibrational density of states, Uo,i is the threshold internal energy for decomposition into the i-th channel, J is the rotational angularGet price

Collisional Decomposition of sf6 gas | NIST

Sep 01, 2000 · Abstract. Insulating gas mixtures containing SF 6 have been promoted to serve as replacements for pure SF 6 in order to reduce SF 6 atmospheric emission. It has been argued that some synergism may be achieved by choosing proper buffer gases in mixtures with SF 6 such that the buffer gases efficiently slow down electrons into an energy range where the electron attachment cross section for SF 6 is large.Get price

Decomposition of gaz sf6 in an RF plasma environment.

The decomposition fraction of sf6 gas [etasf6 gas (C (in)-C (out))/C (in) x 100%] and the mole fraction profile of the products were investigated as functions of input power and feed O2/Sulfr hexafluoride ratio in an SiO2 reactor. The species detected in both insulating gas/Ar and Sulfr hexafluoride/O2/ Ar RF plasmas were SiF4, SO2, Fe2, SO2F2, SOF2, SOF4, S2F10, S2OF10, S2O2F10, and SF4.Get price

Ni-CNT Chemical Sensor for sf6 gas Decomposition Components

Oct 16, 2018 · Considering the concentration range of SF 6 decomposition components generated in SF 6-insulated equipment reported in previous studies [4,25], a series of SF 6 decomposition components concentrations, 1, 10, 50, 100, 200, 300, and 400 ppm, were prepared to analyze the gas-sensing performance of the Ni-CNT gas sensor.Get price

OSA | Photoacoustic H2S Gas Sensor for sf 6 Decomposition

A photoacoustic hydrogen sulfide (H2S) gas sensor for sulfur hexafluoride (sf 6) decomposition analysis in an electric power system was developed. A detection limit of 109 ppb was achieved.Get price

Decomposing Mechanism of gaz sf6 under Positive DC Partial

6 decomposition mechanism under positive DC PD. Thus, the relationships between SF 6 decomposition components and the H 2 O content remain unclear, which may impact the diagnosis accuracy and validity of the faults inside the devices. According to IEC 60480-200518 and IEC 60376-200519 standards, the H 2 O content in SF 6 gasGet price